FTA法在提高冷轧板喷涂表面质量中的应用

冷轧板喷涂表面在生产过程中有许多表面质量缺陷,如表面缩孔缺陷,严重制约冷轧板喷涂的品质和制造成本.为了是提高冷轧板喷涂表面质量,本文运用FTA方法(故障树分析方法),分析某家电外箱体冷轧板喷涂生产过程中形成表面缩孔缺陷的原因,绘制故障树,进行布尔代数计算求出最小割集,提出部分优化措施,最终提升该系列产品的市场竞争力,并为进一步研究提供帮助.     

Spheroidization of molybdenum powder by radio frequency thermal plasma

To control the morphology and particle size of dense spherical molybdenum powder prepared by radio frequency (RF) plasma from irregular molybdenum powder as a precursor, plasma process parameters were optimized in this paper. The effects of the carrier gas flow rate and molybdenum powder feeding rate on the shape and size of the final products were studied. The molybdenum powder morphology was examined using high-resolution scanning electron microscopy. The powder phases were analyzed by X-ray diffraction. The tap density and apparent density of the molybdenum powder were investigated using a Hall flow meter and a Scott volumeter. The optimal process parameters for the spherical molybdenum powder preparation are 50 g/min powder feeding rate and 0.6 m3/h carrier gas rate. In addition, pure spherical molybdenum powder can be obtained from irregular powder, and the tap density is enhanced after plasma processing. The average size is reduced from 72 to 62 μm, and the tap density is increased from 2.7 to 6.2 g/cm3. Therefore, RF plasma is a promising method for the preparation of high-density and high-purity spherical powders.     

Nitridation of chromium powder in ammonia atmosphere

CrN powder was synthesized by nitriding Cr metal in ammonia gas flow, and its chemical reaction mechanism and nitridation process were studied. Through thermodynamic calculations, the Cr-N-O predominance diagrams were constructed for different temperatures. Chromium nitride formed at 7002-1200℃ under relatively higher nitrogen and lower oxygen partial pressures. Phases in the products were then investigated using X-ray diffraction (XRD), and the Cr₂N content varied with reaction temperature and holding time. The results indicate that the Cr metal powder nitridation process can be explained by a diffusion model. Further, Cr₂N formed as an intermediate product because of an incomplete reaction, which was observed by high-resolution transmission electron microscopy (HRTEM). After nitriding at 1000℃ for 20 h, CrN powder with an average grain size of 63 nm was obtained, and the obtained sample was analyzed by using a scanning electron microscope (SEM).     

MW-PLS法对雷尼替丁粉末药品的定量分析

结合可移动窗口偏最小二乘法（MW PLS）, 利用近红外漫反射光谱建立雷尼替丁粉末药品质量分数无损快速检测方法. 对模型进行优化时选择一阶导数、 二阶导数、 卷积平滑和快速Fourier变换预处理方法, 并优化隐变量数等模型参数. 以逼近度Da作为建模参数的优化评价标准, 最终得到测定雷尼替丁粉末药品的最佳模
型. 用该模型进行预测, 其校正集和验证集的预测值和真实值间的相关系数（Rc）分别为0.984 5和0.977 5, 校正集的均方根误差（RMSEC）为0.003 1, 验证集均方根误差（RMSEP）为0.003 3. 与高效液相色谱(HPLC)测定结果比较, 其相对误差≤2.422%.     

不同轮压与厚度下的半刚性橡胶沥青路面结构受力变形与仿真分析

随着国家雄安新区城市建设规划实施,按照雄安新区道路建设15年不小修的建设标准,河北省启动了全域路面加速加载试验装置开发与试验路评价研究专项.本研究采用全域路面加速加载试验装置测试直道半刚性橡胶沥青路面结构性能的各项指标,结合力学分析法与有限元建模计算分析层底弯拉应力与层厚.通过构建有限元模型,分析不同轮压下(0.7、0.9、1.1 MPa)的半刚性橡胶沥青路面各结构层间的应力应变变化规律及相同结构层不同轮压下的受力变形规律.结果表明,沥青路面作为粘弹性体,路面结构受力同时遵循能量耗散原理,自上而下逐渐减小.提出了半刚性胶粉改性沥青路面结构层在不同轮压、不同深度下的应力变化规律,得出了半刚性胶粉改性沥青路面各层在不同荷载下的应力值变化范围与半刚性水泥稳定碎石基层在不同荷载下的应力值变化范围.这些研究成果对今后雄安新区耐久性沥青路面建设起到了重要的理论支撑与技术指导价值.     

废胎胶粉复合改性高黏沥青复配体系

为研究胶粉复合改性高黏沥青复配体系的显著性影响程度及机理,选择废胎胶粉种类、废胎胶粉掺量、SBS掺量、补强剂掺量、增塑剂掺量5个试验变量制备复合改性高黏沥青。设计五因素四水平正交试验,通过极差分析研究各因素对改性沥青针入度、延度、软化点、黏韧性和60 ℃动力黏度5个技术指标的影响。结果表明：补强剂掺量对针入度影响最大,增塑剂次之;胶粉掺量对60 ℃动力黏度影响最大,与补强剂协同作用于软化点;SBS掺量对延度影响最大;粘韧性无明显规律。综合考虑各因素,得出胶粉合金添加剂的较优制备方案是：选择卡车轮胎胶粉,各物料以质量分数计,废胎胶粉：SBS：补强剂：增塑剂=100:24:10:19。较优制备方案下,通过双螺杆挤出工艺制备胶粉合金高黏添加剂,且掺量为25%时,废胎胶粉复合改性高黏沥青表现出优秀的高低温性能,沥青黏度和路用性能明显提升。     

多微孔苄基木粉的制备及其对铜离子的吸附性能

将杉木粉进行苄基化改性反应,再经高温水蒸汽爆破处理制得多微孔苄基木粉,用红外光谱、扫描电镜对杉木粉改性前后的结构进行了表征.以多微孔苄基木粉为吸附剂,用原子吸收光谱研究了体系初始p H值、铜离子浓度、吸附温度和吸附时间等因素对铜离子的吸附效率.结果表明,多微孔苄基木粉对铜离子的吸附能力高于原木粉、脱脂木粉和苄基木粉;当溶液的p H值为4.0、铜离子浓度为40 mg/L、吸附温度为40℃、吸附时间为45min,多微孔苄基木粉质量为溶液质量的0.8%时,铜离子的去除率高达99%.     

铁基粉末的恒流电致快速烧结

采用恒流电致烧结方法对铁基混合粉末进行了快速烧结,通过对不同通电时间烧结样品的显微组织、断口形貌进行分析,并对其电阻、密度及各项机械性能进行测试,研究了粉末的电致烧结行为.结果表明：在较低的测量温度下,粉末中出现了烧结颈,并发生了铁-碳的互扩散,且颗粒界面有局部熔化的迹象,证实电致烧结初期在颗粒接触区域存在局部高温;随着烧结过程的进行,烧结体的密度、横向断裂强度和显微维氏硬度均呈上升趋势,电阻则逐渐降低.     

橡胶板式支座锚栓超低周疲劳断裂分析

为研究螺栓球节点橡胶板式支座中锚栓在灾难地震中受弯剪发生超低周疲劳的断裂问题,依国家现行规规范设计并制作了橡胶板式支座模型,采用双向加载法对其进行了大位移超低周疲劳试验,得到了四根锚栓的超低周疲劳破坏形态。并从宏、微观角度对锚栓断口进行了分析。结果表明：在往复荷载下,锚栓发生无明显塑性变形的较突然性断裂,为超低周破坏形态,其断口存在疲劳源区、扩展区和瞬断区等典型的疲劳断裂特征,且不同位置锚栓的受力方向和裂纹起裂时间、扩展速率均不同;同一锚栓断口上韧性断裂与脆性断裂特征并存,但总体均表现为偏脆性断裂。     

紫外皮粉法测定倍花中单宁酸含量

用紫外皮粉法测定倍花中单宁酸的含量,并对实验结果进行方法学考察.经实验知在20 ℃下溶液的稳定性较好,铬皮粉在20 min后吸附达到完全,平均加标回收率为98.86%,RSD为0.85,精密度和重复性实验的RSD分别为0.07%和0.64%.用紫外皮粉法测试倍花中单宁酸含量得到的结果与用药典法测试得到的结果近似.